It's little sister day at the cafe and Misaki discovers to her horror that she has no idea how to act like a little sister. Not willing to accept that she doesn't know how to do something she sets out to discover how exactly to act like a little sister.
At the same Takumi is his usual unhelpful self. When another girl at school confesses her love for him, his answer is a surprise.
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Ready to Watch Kaichou wa Maid sama, Season 1, Episode 3?